The method uses a ketone and a methyl vinyl ketone to form an α β unsaturated ketone in a cyclohexane ring by a michael addition followed by an aldol condensation.
Vinyl cyclohexane reactions.
This procedure is one of the key methods to form fused ring systems.
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The chemical reaction in this case is a so called ammoximation reaction whereby cyclohexane is reacted with ammonia and hydrogen peroxide at around 90 c in the presence of a titanosilicate catalyst.
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With cyclohexane the average length of the chain hardly exceeds one step and one mole of hydrocarbon reacts with one mole of peroxide.
Table 2 reactions of acyclic vinyl triflates and calculated nonclassical int23 22 24 for insertion of cyclohexane into butenyl cation.
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On a étudié la polymérisation par coordination ionique du vinyl cyclohexane.
Des réactions secondaires par exemple isomérisation en composés inactifs comportant une double liaison interne et la transformation du monomère en éthyle cyclohexane se produisent pendant la polymérisation du vinyl cyclohexane sur les catalyseurs complexés organométalliques.
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